Zac Efron shows up on time for Hublot's celebration of new brand ambassador Kobe Bryant; Jon Hamm, Christina Hendricks, Elisabeth Moss and the rest of the "Mad Men" cast turn out for the Season 6 premiere; Jason Bateman and Emma Rossum make memorable appearances at a gala benefiting the Alzheimer's Association; Neil Patrick Harris attends Hollygrove's Norma Jean Gala; Christina Ricci and Rosie Huntington-Whiteley look stunning at the BlackBerry Z10 launch; Leandra Medine, Liberty Ross and Brooke Davenport shop the Christian Dior pop-up at Maxfield—it was a very busy Hump Day here in L.A. and we have the rundown on it all in today's edition of Last Night's Parties.